IGN:
The Winchesters are back and almost nothing is the same. Six weeks have passed for the brothers since the game-changing Season 9 finale, and Demon Dean is living it up. He's doing karaoke, he's free from angst and guilt, and demon life is good. It's so refreshing to see a different side of the character unfold as Jensen Ackles explores the wild 'n crazy side of Dean. He seems to be having fun with the twist, and it shows.
The premiere episode firmly established just how far gone Dean is. It's not only about a lack of humanity and a penchant for violence, he was willing to let Sam die. Hard as that was to swallow, it's a smart move for the story and necessary to put that in the spotlight in the first episode. That last scene took away the lighter aspects of Demon Dean and slapped you across the face with truth - it stung.
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I don't what's going to happen next or if Dean really is willing to let Sam die rather than help but then he is a demon now and we have to accept that he's a real demon in the real sense of the word.